Dynamics on core excited state

Questions
#1

Hello,

I would like to run a BOMD on an excited state surface. Only issue, the excited state is a core excitation. I know the surface from CVS-ADC calculations (or also CVS-EOM-CCSD). Is it possible to run an AIMD job on surfaces calculated at these levels of theory or is it necessary to use other tricks (like doing CIS after reordering the orbitals)?
Any suggestion is very welcome.

Thank you for the help,
Alessandro

#2

Are you looking to do that at the CVS-ADC level? I don’t think those gradients are implemented.

#3

I could use also CVS-EOM-CCSD or if you have any idea on how to do, the important is to have a decent surface for the core excited state and run the dynamics on that.