Is TSVDW and MBD only working for CHNO atoms (water works) and not for other elemenrs, in particular transition metals?
For TiCl4 the progam chrashes.
$molecule
0  1
Ti       0.000000000      0.000000000      1.090000000
Cl       0.000000000      0.000000000     -1.198000000
Cl      -1.078000000     -1.868000000      1.853000000
Cl       2.157000000      0.000000000      1.853000000
Cl      -1.078000000      1.868000000      1.853000000
$end
$rem
METHOD             PBE
JOB_TYPE          SP
SCF_GUESS          SAD
BASIS              def2-SVP          Basis Set
ECP                def2-ECP
SCF_CONVERGENCE 8
!MBDVDW           TRUE !vdw settings
TSVDW 1
$end
±-----------------------------------------+
|     Calculate Hirshfeld volumes          |
±-----------------------------------------+
Requested basis set is def2-SVP
There are 11 shells and 31 basis functions
A cutoff of  1.0D-12 yielded     66 shell pairs
There are       546 function pairs (       750 Cartesian)
Requested basis set is def2-SVP
There are 11 shells and 31 basis functions
A cutoff of  1.0D-12 yielded     66 shell pairs
There are       546 function pairs (       750 Cartesian)
FileMan error: End of file reached prematurely reading (84872) bytes in file UNKNOWN FILE
Path: /scratch/qchem20314/1657.0: No such file or directory
Q-Chem fatal error occurred in module libmdc/newfileman.C, line 348:
FileMan error: End of file reached prematurely reading (84872) bytes in file UNKNOWN FILE
Path: /scratch/qchem20314/1657.0